Celtic aim to extend their incredible 61-match unbeaten home run this evening and avenge the 1-0 defeat to Anderlecht in Brussels last month.
Since then the Hoops have moved five points clear of Rangers in the Bank of Scotland Premier League and have scored nine goals in their last two games.
Martin O'Neill made just one change from the side which thrashed Kilmarnock 5-0 on Saturday with Didier Agathe replacing Michael Gray, who drops to the bench, which means Irish youngster Liam Miller keeps his place and faces arguably the biggest game of his career.
Victory is vitally important, with Anderlecht and Lyon a point ahead of Celtic in Group A and Bayern Munich leading the way by a further point with just two games left after tonight.
Meanwhile, Dennis Bergkamp, still looking for his first goal this season, was preferred to Sylvain Wiltord in an unchanged Arsenal side that needed victory over the Ukrainians to prolong their Champions League interest this season.
Arsene Wenger's team also needed to break their astonishing European duck of no wins in their eight previous ties stretching back nearly a year to retain any realistic hope of making it through to the quarter-finals this time.
And they started the clash with just one point from three Champions League matches in the group following their defeat in Kiev two weeks ago.
Celtic: Hedman, Varga, Balde, McNamara, Agathe, Miller, Lennon, Sutton, Petrov, Hartson, Larsson. Subs: Douglas, Gray, Sylla, Maloney, Wallace, Mjallby, Kennedy.
Anderlecht: Zitka, Zewlakow, Tihinen, Kompany, Deschacht, Wilhelmsson, Hendrikx, Hasi, Baseggio, Dindane, Mornar. Subs: Peersman, Ilic, Vanderhaeghe, Kolar, Zetterberg, MacDonald, Ngalula Mbuyi.
Arsenal: Lehmann, Lauren, Toure, Campbell, Cole, Ljungberg, Parlour, Silva, Pires, Bergkamp, Henry. Subs: Stack, Wiltord, Edu, Cygan, Clichy, Kanu, Aliadiere.
Dynamo Kiev: Shovkovskiy, Fedorov, Leko, Nesmachnyi, Gavrancic, Ghioane, Shatskikh, Belkevich, Peev, Onyschenko, Gusev. Subs: Alessandro, Melashchenko, El Kaddouri, Rincon, Nanni, Sablic, Reva.